as I read the second post links Joseph_H posted, "6(b)(7) of the Act requiring OSHA to 'insure that employees are apprised of all hazards to which they are exposed,' the Agency concludes that employees must be informed about all potential hazards before the worker is exposed to them".
1926.21(b)(2)
The employer shall instruct each employee in the recognition and avoidance of unsafe conditions and the regulations applicable to his work environment to control or eliminate any hazards or other exposure to illness or injury.
1926.21(b)(3)
Employees required to handle or use poisons, caustics, and other harmful substances shall be instructed regarding the safe handling and use, and be made aware of the potential hazards, personal hygiene, and personal protective measures required.
1926.21(b)(5)
Employees required to handle or use flammable liquids, gases, or toxic materials shall be instructed in the safe handling and use of these materials and made aware of the specific requirements contained in Subparts D, F, and other applicable subparts of this part.
1926.21(b)(6)(i)
All employees required to enter into confined or enclosed spaces shall be instructed as to the nature of the hazards involved, the necessary precautions to be taken, and in the use of protective and emergency equipment required. The employer shall comply with any specific regulations that apply to work in dangerous or potentially dangerous areas.
While I fully agree it is each persons responsibility for their own safety, I doubt it to be a "best practice" or even allowable by law to just expect the employee to be able to just protect themselves.
Rick_c asks "how many of us / you have read the msds for brake cleaner or carb cleaner?" I would like everyone to read the MSDS for used motor oil too... I know I do when I train a new tech. It might slow down folks who reach into the pan with bare hands to pick up the drain plug.
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